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J. Biochem, 1995, Vol. 118, No. 3 552-554
© 1995 Japanese Biochemical Society

other

Determination of the Absolute Configuration of Urothion

Atsushi Sakural1, Hideki Horibe, Nobuhiro Kuboyama, Yuji Hashimoto and Yasuaki Okumura

Department of Chemistry, Faculty of Science, Shizuoka University Ohya, Shizuoka 422

1To whom correspondence should be addressed.

In order to determine the absolute configuration of urothion (1), the CD spectra of tri-4-chlorobenzoyl derivatives of 2-amino-6-[(3R)-3, 4-dihydroxybuty1]pteridin-4(3H)-one and its (3S) compound were compared with that of the tri-4-chlorobenzoyl derivative obtained from the natural product. R-Configuration was concluded for the secondary hydroxyl group on the side chain of 1, which is the same configuration as that of molybdopterin (2). This supports the view that 1 might be a urinary metabolite of 2.


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