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Journal of Biochemistry 2004 136(5):643-649; doi:10.1093/jb/mvh172
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© 2004 The Japanese Biochemical Society

BIOTECHNOLOGY

Design, Expression and Characterization of Collagen-Like Proteins Based on the Cell Adhesive and Crosslinking Sequences Derived from Native Collagens

Juming Yao, Satoshi Yanagisawa and Tetsuo Asakura*

Department of Biotechnology, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588

Two recombinant collagen-like proteins consisting of cell adhesion domains derived from native type I collagen were designed and synthesized by a genetic engineering method. The cross-linking sequence, GPPGPCCGGG, derived from collagen III was used to promote triple helix formation through the disulfide bonds formed among three chains by flanking the peptide at the C-terminal of the collagen-like proteins. SDS-PAGE and western-blotting data suggested possibility of the formation of a triple helix structure for both recombinant proteins. CD spectra and thermal stability analyses indicated that the triple-helix structure in the collagen-like proteins was pH-dependent and stabilized under acidic environmental condition. Moreover, the collagen-like protein flanked with the cross-linking sequence at the C-terminal showed the most stable triple-helical conformation under acidic conditions.

* To whom correspondence should be addressed. Tel/Fax: +81-42-383-7733, E-mail: asakura{at}cc.tuat.ac.jp


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